************************************************************* TERRA-KLEEN RESPONSE GROUP, INC. (Solvent Extraction Treatment System) This vendor is participating in the EPA Superfund Innovative Technology Evaluation (SITE) Program. The following technology profile has been reproduced from the SITE Technology Profile document, 7th edition. The SITE profile has been supplemented by MVA Consulting Inc. using information obtained from the vendor or from other SITE publications, referenced at the end of this file. TECHNOLOGY DESCRIPTION: The solvent extraction treatment system was developed by Terra-Kleen Response Group, Inc. (Terra-Kleen), to remove semivolatile and non-volatile organic contaminants from soil. This batch process system uses a proprietary solvent blend to separate hazardous constituents from soils, sediments, sludge, and debris. The U.S. EPA Office of Pesticides and Toxic Substances has made a written finding that the Terra-Kleen solvent is nontoxic. A schematic diagram of the Terra-Kleen treat-ment system is shown below. Treatment begins after excavated soil is loaded into the extraction tanks. Clean solvent from the solvent storage tank is pumped into the extraction tanks. The soil and solvent mixture is held in the extraction tank for a time period sufficient to solubilize organic contaminants into the solvent, separating them from the soil. The contaminant-laden solvent is then removed from the extraction tanks and pumped into the sedimentation tanks. Suspended solids settle or are flocculated in the sedimentation tank, and are then removed. Following solvent extraction of the organic con-taminants, any residual solvent in the soil is removed using soil vapor extraction and biological treatment. Soil vapor extraction removes the majority of the residual solvent, while biological treatment reduces residual solvent to trace levels. The treated soils are then removed from the extraction tanks. The solvent regeneration process begins by pumping contaminant- laden solvent from the sedimentation tank through a microfiltration unit and a proprietary solvent purification station. The microfiltration unit first removes any fines remaining in the solvent. The solvent purification station separates organic contaminants from the solvent and concentrates them, reducing the amount of hazardous waste for off-site disposal. The regenerated solvent is pumped into the clean solvent storage tank for use in treating additional soil. WASTE APPLICABILITY: The Terra-Kleen solvent extraction treatment system is a waste minimization process designed to remove the following organic contaminants from soils: polychlorinated biphenyls (PCB), chlorinated pesticides, polycyclic aromatic hydrocarbons (PAH), pentachlorophenol, creo-sote, polychlorinated dibenzo-p-dioxins (PCDD), and polychlorinated dibenzofurans (PCDF). The technology also has the capacity to remove organic contaminants, such as PCBs, from low- level radioactive wastes. The Terra-Kleen solvent extraction system does not require soil screening equipment to remove debris or large objects from the contaminated soil before treatment. The system is trans-portable and can be configured to treat small quantities of soil (1 to 1,000 cubic yards) as well as large volumes generated at remedial sites. STATUS: Terra-Kleen demonstrated its solvent extraction treatment system under the SITE Demonstration Program between May 16 and June 11, 1994. The technology was demonstrated at the Naval Air Station North Island Site 4, in San Diego, California. Soils at Site 4 are contaminated with heavy metals, volatile organic compounds (VOC), semivolatile organic compounds (SVOC) (including PAHs), PCBs (Aroclor 1260), dioxins, and furans. DEMONSTRATION RESULTS: Preliminary findings from the Terra-Kleen SITE demonstration are summarized as follows: > PCB Aroclor 1260 concentrations were reduced from a maximum of 170 milligrams per kilogram (mg/kg) in untreated soil to approximately 2 mg/kg in treated soil. The average removal efficiency was 98.39 percent. > The system can efficiently concentrate PCBs into a smaller waste volume for off-site disposal. > The treatment system's PCB removal efficiency was reproducible for all batches run during this demonstration. To provide additional information on the tech-nology's capabilities, samples were also collected and analyzed for VOCs, SVOCs, PCDD, and PCDF. The analytical data from these samples are not yet available. All findings of the Terra-Kleen SITE demonstration, including sample analytical results, will be discussed in the SITE technology capsule and the innovative technology evaluation report. Additional data is being collected at the Naval Communication Station in Stockton, California. The system is treating soil contaminated with chlorinated pesticides at concentrations up to 600 mg/kg. Preliminary data indicates that target levels of 1 mg/kg are being achieved. FOR FURTHER INFORMATION: EPA PROJECT MANAGER: Mark Meckes U.S. EPA Risk Reduction Engineering Laboratory 26 West Martin Luther King Drive Cincinnati, OH 45268 513-569-7348 Fax: 513-569-7676 TECHNOLOGY DEVELOPER CONTACT: Alan Cash Terra-Kleen Response Group, Inc. 7321 North Hammond Avenue Oklahoma City, OK 73132 405-728-0001 Fax: 405-728-0016 __________________________________________________________ Sources of information in this profile: EPA Superfund Innovative Technology Evaluation Program Technology Profiles Seventh Edition, November 1994. EPA/540/R-94/526. *************************************************************