Amendment No. 1 to Final Mini Quality Assurance Project Plan and Remedy Development Activities at the Lemon Lane Landfill Prepared for the EPA by EARTH TECH May 1995, Amended October 1996 PRELIMINARY DRAFT - SUBJECT TO REVISION INTRODUCTION The purpose of this amendment is to expand the scope of oversight activities to be conducted at the Lemon Lane Landfill site. Westinghouse has agreed to install 25 test borings in the landfill, install piezometers, and obtain waste and soil samples for PCB anaIyses to evaluate the extent of PCB "hot spots" in the landfill. Earth Tech will conduct oversight of all Westinghouse investigations as directed by the WAM. Concurrent with Westinghouse activities, seven test borings (as requested by the City of Bloomington and Indiana Department of Environmental Management) will be installed by EARTH TECH to evaluate the possibility of the existence of PCB "hot spots" in other suspect areas. To include the additional work to be covered under the Mini-QAPP, the following sections are herein amended. Section 1.2.1 Summary of Oversight Activities (new Section) Section 4.2.1 Sampling Procedures (new Section) Figure 1-5 Boring Location Map (new Figure) Table B-11 Surnrnary Test Boring Soil and Waste Sampling and Analysis Program, Lemon Lane Landfill (new Table) Table B-12 Summary Test Boring, Liquid Sampling and Analysis Program, Lemon Lane Landfill (new Table) Appendix D Standard Operating Procedures A-12, A- 19, A-29 (new Appendix) 1.2.1 OVERSIGHT OF HOT SPOT lNVESTIGATION Westinghouse has agreed to install 25 test borings (Figure 1-5, Borings SB-1 through SB-25) at Lemon Lane Landfill through the buried waste and into natural soils below the waste. The purposes of this phase of the Westinghouse investigations are to: * Evaluate the horizontal and vertical extent of PCB contamination in the known hot spot areas. *evaluate PCB contamination in the two sinkholes at the site, *evaluate the electromagnetic survey anomalies for PCB contamination, and *evaluate the potential for hot spot material to be RCRA characteristic waste. Westinghouse will obtain composites for PCB analyses of 2 and 4 foot sample intervals. Each test boring will be continuously sampled. Earth Tech will conduct oversight of "key" activities as requested by the WAM. All oversight activities will be conducted and documented as specified in Section 1.2 (Summary of Oversight Activities). The oversight activities include obtaining splits of natural soil samples collected below the waste from three of the eight test borings located in the two sinkhole areas on site (Figure 1-5). Table B-ll in Appendix B summarizes the sample matrix, analytical parameters, DQOs and frequency of sample collection. These soil samples will be submitted to the Region 5 CRL for SAS Pesticide/PCB analyses using Method SW- 846-8081, and to a Region 5 contracted lab for SAS Dioxin/Furan analyses. The oversight activities also include obtaining liquid samples, if present, from the bottom of 4 of the deep borings located in the two sinkholes. If liquids are encountered, samples will be obtained using dedicated bailers (SOP A-12, Appendix D) through the hollow stem augers prior to closure of the test boring. These liquid samples will be sent to a CLP lab as scheduled by Region 5 for TCL organics and TAL inorganic analyses, and to a Region 5 contract lab for SAS Dioxin/Furan analyses. Table B-12 in Appendix B summarizes the sample matrix, analytical parameters, DQOs and frequency of sample collection. In addition to oversight of Westingnouse activities, EARTH TECH, at the direction of the WAM, will install seven test borings (Figure 1-5, Borings SB-26 through SB-32) through the waste and into the top of natural soil below the waste. Waste and natural soil will be continuously sampled with split barrel samplers (SOP A-19, Appendix D). The seven boring locations were selected by the City of Bloomington and the Indiana Department of Environmental Management for the purpose of investigating the possibility of the occurrence of PCB contamination in suspect areas, particularly, along old access roads, along surface drainage areas, and in areas in close proximity to known or suspected PCB contamination. It is estimated that the seven test borings will average 20 feet or less in depth, and that about 10 samples will be collected from each boring for PCB analysis. 4.2.1 LANDlILL SAMPLING PROCEDURES The seven test borings will be advanced using hollow stem auger drilling and samples will be obtained using a 2-foot split-barrel (SOP A-19, Appendi~c D) or direct push techniques. All borings will be carefully advanced, through the interim cap covering the landfi11, to minimize damage to the cap. The cap consists of a 36 mil Hypalon cover overlying 6 inches to 5 feet soil, which overlies a 15 rnil Typar stabilization fabric. Sampling will begin once the boring has penetrated the Typar fabric. Sampling will continue through the waste to natural soil material below the waste. If an obstruction is encountered preventing full penetration, the boring will be offset and redrilled. Auger cuttings will be temporarily stored on plastic and placed in the boring after completion of sampling. The bottom of each boring (that section below waste) will be plugged with bentonite. After each boring has been backfilled, the Hypalon cover will be repaired to prevent infiltration of water into the waste. Upon retrieval of each 2-foot split-barrel sample, the sampling device will be opened and the contents described on standard boring logs. The 2-foot sample will be homogenized, placed in an appropriate container for shipment to the CRL for Pesticide/PCB analysis using Method SW846-8081. Duplicate and matrix spike/matrix spike duplicate samples will be obtained as described in Section 4.2 (Sampling Procedures). Sample custody procedures are described in Section 5.0 (Sample Custody), including field logbook and documentation procedures. Table 4-1 provides the requirements for sample containers, preservation, shipping and packaging. All drilling and sampling equipment that comes in contact with waste or soil from below the cap will be decontaminated as specified in SOP A-29 (Appendix D). MONITORING WELL PURGING AND SAMPLING BAILER METHOD SCOPE Obtain a representative sample of the ground water from the formation in which the well screen has been placed. METHOD SUMMARY Ground water is withdrawn from a monitoring well with a bailer, and transferred to the appropriate equipment or containers. Prior to sampling, the well is purged of standing water, using the same bailer. The procedures for determining the static water level and the volume of water standing in the well are given in SOPs A-24 and A-26, respectively. EQUIPMENT/INSTRUMENTS * Water level tape (electric or steel) *Cable or rope (dedicated, one per well; material type as as required by plan/manager) *Bailers (dedicated, one per well; material type as required by plan/manager) *Calculator * Well keys *Container for purge water (if required) MATERIALS/REAGENTS/PREREQUISITE DATA *Detailed well location map *Total well depth data *Disposable gloves * Sample containers & labels * Previous water level data *Static water level *Order of the well sampling (per work plan/project manager) *Calculated well casing volume *Chain-of-Custody record forms Refer to SOP A-24 for determining the static water level in a monitoring well. Refer to SOP A-26 for calculating the volume of standing water in a well casing. All bailers and cables will be decontaminated and wrapped in clear plastic sleeves before being taken to the ffeld. PROCEDURES 1. Unlock each well and remove cap. Care must be taken not to mix the caps up. The caps should be placed near the well on a clean area, such as a small piece of plastic. Inspect the condition of the well(s). 2. Purge the well with a clean or dedicated bailer and cable. Concentrate the purging effort at the air/water interface. (Refer to SOPs A-24 and A-26 determination of static water level, and calculation of purge volume.) Do not allow bailer or cable to contact ground or other potentially contaminated surfaces. Raise and lower the bailer in the well with smooth, controlled motions. Do not allow the bailer to free fall, and avoid sudden' jerky motions. 3. Record the amount of water actually purged and what was done with the purge water. Record the identification number of the bailer used. 4. Collect the ground water sample with the bailer. 5. Fill the sample container(s) by pouring water from the bailer into the appropriate container(s). Collect VOC samples first, then SVOCs, then others, as required. If filtration is required, reserve an aliquot of water in a clean container for processing prior to transfer to the final sample container. Do not allow sample containers or lids to contact potentially contaminated surfaces. 6. Seal the container(s). 7. If the container is a VOC vial, turn the full container upside down and tap it lightly. Watch for air bubbles. If air is present in the bottle, add more water and recap, again checking for the presence of air bubbles. 8. Label the sample container(s) and place in a cooler with ice for transport to the laboratory. 9. Replace bailer and cable in plastic sleeve and mark "USED" on sleeve with an indelible marker. 10. Install well cap, and lock the well. In wells which do not readily recover, it may be unreasonable to purge an arbitrarily prescribed volume prior to sampling. In these cases, a field judgment must be made as to what is a "reasonable" amount of time to spend in securing the sample. In a well that can be bailed dry, it is acceptable to purge the well dry, wait for the well to recover, and take a sample. Keep good records of the volume of water actually purged and estimate the recovery time for the well. The purpose of purging is to remove all the static water from the well. In a well that is bailed dry, that objective is obtained after after the well is initially bailed dry. QUALITY CONTROL Each well will be sampled with a clean, dedicated bailer. Samples will be processed and/or contained only in new or appropriately decontaminated equipment and containers. Well caps, bailers, cables, and container lids will not be placed in contact with any potentially contaminated surface. Sample custody will be maintained through use of a Chain-of-Custody record form. Purge water will be properly handled per applicable regulations and work plans. RECORDS/REPORTING Record all observations, measurements, and activities on the appropriate forms or in a log book. Include the following information. *Date and time of sampling *Project name, number, and location *General weather conditions *Name and responsibility of each person involved, including WWES personnel, client representative(s), regulatory observer(s) and/or visitor(s), as applicable *Description/identification of all equipment used *Accurate description of sample location *All measurements, and accomplishments, and observations including noticeabe discoloration or odor in the water *Any difficulties encountered * Disposition of purge water * General condition of well Record all samples on a Chain-of-Custody form, completed prior to, and included in the sample shipment. HEALTH AND SAFETY Potential health and safety concerns during monitoring well sampling include the following. * Exposure to extreme weather conditions * Exposure to environmental contaminants * Exposure to chemical reagents used as sample preservatives *Slip, trip and fall hazards *Exposure to insects, rodents, snakes, etc. Sampling personnel should use appropriate personal protective equipment as specified in a site health and safety plan. SPLIT SPOON SAMPLING Obtain soil samples for identification and classification from specified intervals. Collect soil samples for laboratory analyses, if required. METHOD DESCRIPTlON Soil samples are collected with a split-spoon or split-barrel sampling device. The samples may be used to determine the physical soil characteristics and/or for chemical analyses. The sampling method is described by ASTM Method D-1586 and is summarized in this SOP. The split spoon technique uses a standard 2-inch diameter split-barrel device to retrieve a sample of soil material from a previously selected interval. The split spoon is driven into undisturbed soil below a hollow stem auger with a 140 lb. weight free-falling a distance of 30 inches. The split spoon is returned to the surface; opened, and the sample is collected. The standard split spoon for geotechnical studies is 18 inches long. Environmental investigations may be performed with 18 or 24 inch split spoons. During a geotechnical study (i.e., a study designed to determine the compressive strength of the soil for the purpose of new building construction) split spoon samples are usually collected at the rate of one sample per 2.5-foot interval in the first 10 feet below grade and one sample per 5-foot interval thereafter, to the bottom of the boring. During an environmental investigation soil samples are collected from depths most likely to show environmental effects based on an evaluation of the known or suspected contaminants, the characteristics of the soils, and other variables that may affect a particular site. EQUIPMENT/INSTRUMENTS *Drilling and sampling devices (usually provided by subcontractor) *Decontamination equipment *Sampling tools (spatula, knife, etc.) *Air monitoring equipment *Ruler or measuring tape (if required) MATERIALS/REAGENTS/PREREQUISITE DATA *Boring locations *Sample intervals *Boring log forms *Sample containers & labels *Dilute HC1 *Disposable gloves *Personal protective equipment (if required) *Containers for drill cuttings (if required) *Munsell color chart for soil *Chain-of-Custody record forms PROCEDURE PREPARATION Prior to each use, split-spoons should be washed in a detergent solution and rinsed with potable water. This is easily accomplished by immersing the spoons in wash and rinse solutions prepared in buckets. If a split spoon is to be used to collect a sample for chemical analysis, additional decontamination and preparation may be required. Refer to project management personnel and/or project-specific Work Plans for details. Refer to SOP A-29 for decontamination procedures. If a soil sample will be collected for analysis of Volatile Organic Compounds (VOCs), install the appropriate liner tubes in the split spoon following decontamination of the split spoon. COLLECTION OF SAMPLES FOR PHYSICAL EVALUATION (GEOTECHNICAL) 1. Locate each boring by physical measurement (distances and/or angles) to permanent objects, or by grid coordinates, and plot each location on a sketch map or base map. 2. Advance the boring to the desired sampling depth. 3. Attach the split-spoon sampling device to the bottom end of the drilling rods and gently lower it to the bottom of the borehole. 4. Drive the split spoon into the undisturbed soil below the lead auger. The split spoon should be advanced 18 or 24 inches (depending on the length of the spoon), unless refusal occurs. 5. Record the number of blows required to drive the sampler for each 6-inch increment. If the soil is particularly hard and the blow counts are in excess of 100 blows per 6 inches, a split spoon may not be capable of obtaining the sample. To avoid damaging the sampling device, terminate the sampling attempt, record observations, and advance the augers to the next sample interval. 6. Bring the split spoon back to the ground surface after it has been driven over the sample interval. 7. Open the split spoon. If samples are to be collected for chemical analysis, refer to procedures in the next section of this SOP 8. Visually inspect the sample and describe it accurately and completely on a soil boring log form, if required. Residual soil from within the augers may become entrained in the split spoon during sampling; hence, the upper portion of soil in the split spoon may be disturbed or not representative of the targeted sample interval. The upper portion should be observed, but field judgment should be used as to whether it is representative of the sample interval. The upper portion should not be collected for lab analyses. COLLECTION OF SAMPLES FOR CHEMICAL ANALYSIS (ENVIRONMENTAL) 9. Collect and screen a sample for organic vapors (if required). (Refer to SOP A-34). 10. Deter nine the sampling interval, either by identifying soil that is most likely to be affected by environmental contaminants based on screening results and visual observations or by reference to project-specific Work Plans. Collect samples into the appropriate containers. If liner tubes are used, the tubes serve as the container. Remove the tubes from the split spoon, install end caps and label the tube. Indicate complete sample identification in accordance with project specifications, and identify "top" and "bottom" of tube. If liner tubes are not used, transfer soil from the split spoon to the appropriate containers using a clean tool.. Collect samples to be analyzed for volatile organic compounds first, followed by samples for semi-volatile then inorganics. INTERFERENCES Sampling objectives may be compromised by any of the following circumstances. *Physical obstructions to sample collection *Improper decontamination * Poor sample recovery *Cross contamination with other soil during split spoon driving/recovery, or during sample inspection/collection QUALITY CONTROL All soil boring well construction data will be recorded on the standard well/boring log forms. All tools and material used in subsurface applications will be properly decontaminated prior to each use. Soil boring installation and soil sampling will be performed at locations identified, and using procedures described, in approved work plans or proposals, where applicable. Any variations will be discussed with, and alternatives approved by, the project manager prior to implementation. Soil cuttings, development water, and other byproducts or waste materials generated during sampling activities will be properly handled per applicable regulations and work plans. Potable water used during drilling and sampling may be sampled for selected chemical analyses prior to use, if required. . RECORDS/REPORTING Record all observations, measuremen-ts and accomplishments on the appropriate forms or log book. Field notes should include the following information. *Date and time of observation/activity *Project name, number, and location *General weather conditions *Name and responsibility of each person involved, including EARTH TECH personnel, client representative(s), regulatory observer(s) and/or visitor(s), as applicable *Description of equipment and material used (HSA diameter; type of sampler) *Location of boring * Depth intervals and physical description of soil samples *Air monitoring data, if monitored *Any unusual features observed, difficulties encountered, etc. HEALTH AND SAFETY Potential health and safety concerns during soil boring and split spoon sampling include the following. *Exposure to extreme weather conditions *Overhead and underground utilities *Overhead obstructions/falling objects *Excessive noise *Exposure to environmental contaminants Sampling activities should be conducted in accordance with an approved site health and safety plan. REFERENCES ASTM, 1985. Annual Book of ASTM Standards, Volume 4.08, pp. 298-303 (Method 1586-84). American Society for Testing and Materialsj Philadelphia, PA, March, 1985. DECONTAMINATION OF SAMPLING EQUIPMENT SCOPE Decontaminate sampling equipment to be used in the collection of environmental samples for chemical analyses. METHOD DESCRIPTION This SOP describes procedures for decontamination of split-spoon sampling devices, temporary well materials, augers, water sampling pumps, tubing, bailers, dippers, scoops, and other non- dedicated equipment used for obtaining samples for field or laboratory analyses. These procedures are intended to minimize incidents of cross-contamination between successive samples in a given investigation, and between successive investigative sites. Decontamination procedures vary depending on parameter types and characteristics. Specific procedures are given herein for inorganic parameters and for organic parameters. Decontamination procedures apply . to equipment which may come in contact with these parameter types, whether the parameters are present within a soil or water matrix or as a "free" liquid. EQUIPMENT/INSTRUMENTS Pressure washer (hot water-high pressurellow volume) or steam cleaner as required *High pressure wand *Hose(s) *Brushes *Sprayer (garden/weed type) *Squirt bottle *Containers for spent solutions (if required) MATERIALS/REAGENTS/PREREQUISITE DATA Alconox detergent *Disposable gloves *Solvents or acids, if required *Deionized water PROCEDURE DECONTAMINATION FREQUENCY With a few exceptions to be mentioned, all named equipment should receive the same kind of decontamination. All augers and other equipment provided by the contractor should be decontaminated upon arrival at the site. Equipment provided by EARTH TECH that has not been decontaminated and suitably protected before and during transport to the site also should be decontaminated upon arrival. All down-hole drilling tools should be decontaminated prior to use at each boring location. Soil samplers (e.g., split spoons, continuous samplers, etc.) should be decontaminated thoroughly prior to each collection of a laboratory analytical sample. Samplers should be washed with a detergent solution and rinsed with tap water prior to collection of any other samples (e.g., soil for visual examination/classification). Temporary well materials, as well as pumps and bailers used for well development or redevelopment should be decontaminated before each use. METHODS Specific procedures are described in the following sections. In general, wash and rinse "heavy equipment" such as drilling augers, rods, split barrel samplers, etc. using a pressure washer. Wash "hand tools" such as hand augers, shovels, scoops, spatulas, etc. manually in a bath by immersion with agitation or scrubbing and rinse by immersion or spraying. Only those tools coming into direct contact with the medium to be sampled need be subjected to the solvent rinses described. Decontamination of other equipment (e.g., augers used to advance a boring for split-spoon sampling of soil) may be limited to a detergent wash and tap water rinse. ORGANIC PARAMETERS Wash equipment with a non-phosphate detergent solution (e.g., Alconox and water). Tap water may be used as feed water; however, be sure the feed water is taken from a public water supply or a source of known and approved quality. Ensure that all parts of the equipment subject to decontamination come in contact with the solution either by directing the sprayer appropriately or by immersion and scrubbing. Rinse equipment with water from the same source as that used in making the detergent solution. Rinse equipment with deionized water Rinse equipment with reagent-grade acetone (*) Rinse with pesticide-grade hexane or methyl alcohol (*) (*) If either acetone, hexane or methyl alcohol is a target analytical parameter for the investigation, select an alternative solvent. Refer to project management personnel and project- specific work plans for selection criteria. Allow equipment to air-dry INORGANIC PARAMETERS Wash equipment with a detergent shlution, either by bathing the equipment in a tub or by spraying equipment with a pressure washer. Scrub with brushes if necessary. Rinse equipment with dilute (O. 1N) hydrochloric acid or dilute nitric acid. Rinse with tap water Rinse with deionized water. If decontaminated equipment must be stored prior to use, place it in new plastic bags or wrap it in new plastic sheeting. ON-SITE STORAGE AND DISPOSAL OF DECONTAMINATION FLUIDS Store all fresh and spent decontamination fluids in appropriately labeled containers with proper spill control/containment, and adequate security. Properly dispose of all decontamination liquids. Refer to project management personnel, project- specific work plans or similar specifications for appropriate management of these materials. All procedures implemented should be in conformance with applicable environmental rules and civil codes, client directives and project-specific work plans and health and safety plans. RECOMMENDATIONS The following suggestions provide for a more efficient decontamination system; however, specific characteristics of each project will limit the applicability of some or all recommendations. The specific decontamination program should first follow approved work plans and/or project-specific guidelines, and maximize the use of these recommendations. Detergent solution, DI water and reagents may be prepared in, stored in and dispensed from sprayers or squirt bottles. In this manner, each decontamination fluid remains clean. Tap water may be handled similarly; however, continuous flow from the tap is preferred. If any decontamination solution must be prepared in a tank or tub, and decontamination is performed by immersion/bathing, the following general guidelines should be considered in order to minimize the need for changing the solutions. *Wash cleaner (less soiled or "oily") equipment first. *Have several of each tool on hand, where practical, to save decontamination time and to allow washing equipment in a batch. If a tap water bath is used change the tap water when it first shows discoloration, floating debris, or foaming tendencies due to soap-carryover. T vo tap water baths in series, changing out both when the second bath reaches the above condition, will minimize changes. Detergent solutions should be changed at least as frequently as the rinse bath, or more frequently if the solution shows a slick that is other than detergent film. Change the detergent solution when it no longer generates foam with moderate agitation. Personal judgment also may be used to determine the need for fresh solution due to an accumulation of suspended clay or silt. Have sufficient containment capacity on hand to be able to change solutions "more" frequently rather than "less". REFERENCES U.S. EPA, 1991. Chapter 11 (Final Draft) Test Methods for Evaluating Solid Waste, Physical/Chemical Methods (SW-846) . U.S. EPA, Office of Solid Waste, Government Printing Office, Washington, D.C., October, 1991.