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1
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2
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- Issues Identified by Parties in December Meeting
- Four Issue Categories (Remedial, Cost, NRD, CD Amendment)
- Resolve Issues Concurrently
- EPA Developing Schedule
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3
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- Status Report for Water, Sediment and Fish Nearly Complete
- Sampling/Analysis of Fish in Conard’s Branch and Richland Creek Complete
and Report Released
- Discussed Obtaining Information with Rogers Group
- Discussing Gas Vent Sampling
- Draft Treatability Study Results
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4
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- Long-Term Groundwater Monitoring Plan
- Required Under SOW
- Minor Issues Remain Before Approval
- Biweekly Influent Samples at Water Treatment Plant
- Monthly Grabs from North and South Spring PCBs/TSS
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5
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- Long-Term Groundwater Monitoring Plan
- Flow/Conductivity During Non-Storm Conditions
- Minimum of 1 Storm/Year >4000
gpm
- Branham and Taylor Springs Semi-Annually
- Piezometer Monitoring Within Landfill
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6
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- Long-Term Groundwater Monitoring Plan
- Water Levels in Monitoring Well 5A
- Fish Sampling in 2004
- Reports Submitted 2/year
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7
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- Groundwater Investigation Plan
- Basin Investigation Including Rogers Quarry
- Aerial Photograph Analysis
- Review Field Stone Records in Detail
- Water Level Data in Monitoring Wells
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8
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- Groundwater Investigation Plan
- Periodic Updates of EPA Status Report
- Dye Trace Decision for Cave Creek in Spring 2002
- Interim Reports Submitted Quarterly
- Final Report August 2002 – Phased Approach
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9
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10
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11
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- Flow records June 6, 2000 to November 14, 2001
- Gage 0, Parshall Flume – Northwest Spring System Overflow 0
- Gage 012, V-Notch Weir, - Overflows 0, 1 and 2
- Gage 34, V-Notch Weir, - Overflows 3 and 4
- Gage NS, V- Notch Weir, - North Spring Overflow
- Q Conard’s Branch Gage = Q Gage 012 + Q Gage
34 + Q South Spring Spillover
- Official USGS Gaging Stations – Water Resources Data for Indiana Water
Year 2000
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12
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- Overlap of records for period October 9 to November 14, 2001
- Summed flow from Gages 012 and 34 compares well with new Viacom gage at
Conard’s Branch
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13
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14
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15
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16
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17
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18
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19
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- August 6 – 8
- Combined effort
- Conard’s Branch and Richland Creek
- Whole-body fish and fillets
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20
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- Conard’s Branch – 1 [CBS #1]
- Richland Creek
- 2 – S of West Vernal Pike bridge [CBS #2]
- 3 – S of Rts 43/48 intersection
- 4 – Rt 43 bridge S of Hendricksville [CBS #3]
- 5 – near 490N/800 intersection NW of Solsberry
- 6 – Rt 54 bridge E of Bloomfield
- [previous CBS sample stations]
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21
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22
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- BRH – black redhorse (4 – 6)
- CP – carp (5 – 6)
- CRC - creek chub (1 and 3)
- GS – green sunfish (1)
- LS – longear sunfish (2 and 4 – 6)
- WS – white sucker (2 and 4)
- (Reach in which each species was collected)
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23
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- USEPA – whole-body fish and fillets
- Total PCBs (Aroclor 1248)
- Did not detect 1016, 1221, 1232, 1242, 1254, 1260
- PCB congeners (14 dioxin-like)
- 77, 81, 105, 114, 118, 123, 126, 157/156, 167, 169, 170, 180/193, 189
- IDEM – fillets
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24
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25
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26
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- Receptors:
- Chemical basis:
- Total PCBs (Aroclor data)
- TEQ – [dioxin] toxic equivalents (congener data)
- Sum of congener-specific risks
- (kingfisher egg only)
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27
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- Exposure assumptions
- 100 % aquatic diet (whole-body fish)
- 100 % foraging within a given reach
- Opportunistic feeding (no species preference)
- Data reduction
- Species mean – average concentration in a particular species within a
single reach
- Reach mean – average of the species means
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28
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- Based on concentrations in prey
- NOAEC – no observed adverse effect conc.
- Highest concentration with no reproductive effect
- LOAEC – lowest observed adverse effect conc.
- Lowest conc. causing adverse reproductive effect
- PCB – geometric mean of 4 mink studies
- TEQ – geometric mean of 3 mink studies
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29
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30
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31
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32
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33
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- Based on dose (ingestion/bodyweight/day)
- NOAEL – no observed adverse effect level
- Highest dose with no reproductive effect
- LOAEL – lowest observed adverse effect level
- Lowest dose causing adverse reproductive effect
- PCB – geometric mean of 3 chicken studies
- TEQ – single chicken study
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34
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35
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36
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- Model accumulation in eggs
- Diet-to-egg biomagnification factors (BMF)
- Based on alewife-to-gull egg BMFs (L. Ontario) for PCB congeners and
total PCBs
- Modeled egg congener conc. converted to TEQ
- Compare modeled accumulation to egg NOAEC and LOAEC for chickens
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37
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- PCBs – geometric mean of 3 studies
- TEQ – single dioxin study
- Based on hatchability and chick survival
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38
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39
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40
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- Third approach for assessing risk to eggs
- Congener-specific risks (77, 105, 126 only)
- Each congener risk based on single study
- Individual risks summed to hazard index (HI)
- Results – Reaches 1 and 2 above lowest effect
- Reach 3 near no effect
- Reaches 4 – 6 below no effect
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41
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- Conard’s Branch
- #1 – 6 to 70 times above lowest
effect
- Richland Creek
- #2 – 1.3 to 10 times above lowest effect
- #3 and 4 – 0 to 2 times above lowest effect
- 0 to 6 times above no effect
- #5 < lowest effect, 0 to 1.7 times above no effect
- #6 – below no effect
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42
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- USEPA Region 5 (SRT-6J)
- 77 W. Jackson Blvd.
- Chicago, IL 60604
- 312 886 7195
- 312 353 5541 (fax)
- chapman.james@epa.gov
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43
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- Developing Status Report for Bennett’s Dump – Summarize Water, Sediment
and Fish Data
- Minor Issues Remain for both Groundwater Monitoring Plan and Groundwater
Investigation Plan
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44
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- Developing Five-Year Review for the Site
- Viacom Agreed to Groundwater Investigation but No Agency Document
- Further Investigation is Necessary Prior to Determination on Addressing
Contaminated Springs
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45
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- Any Concerns on Issues at Bennett’s Dump Can be Sent to the Following:
- Thomas Alcamo
- U.S. EPA Region V
- 77 W. Jackson
- Mail Code SR-6J
- Chicago, IL 60604
- Alcamo.Thomas@epa.gov
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46
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- Pursuant to SOW
- Quarterly PCB Sampling of Middle & Mound Springs
- North and Mid-North Quarterly if Flowing
- Quarterly PCB Sampling Upstream and Downstream in Stout’s Creek
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47
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- Creek Flow Measured Continuously
- Minimum of One Storm Event Sampling
- In 2003, Fish and Sediment Sampling (?)
- Semi-Annual Monitoring of MW 6I, 6D and 5(?)
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48
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- Objectives
- Define Site Hydrogeology and Recharge Area (relationship between gw
elevations, water levels in quarry pits and spring flows)
- Monitor PCBs into Stout’s Creek under varying hydrogeologic conditions
- Determine Impact of Route 46 Highway Construction
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49
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- Air Photo Analysis
- New Topographic Map
- Install Staff Gages in Quarry Pits
- Stream Gaging in Stout’s Creek
- V-Notch weirs on Middle and Mound Spring
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50
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- Piezometer in Grid H7
- Quarterly Reports and Summary Report End of 2002 – Phased Approach
- Periodic Pumping of MW 5 and Evaluate
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51
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52
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53
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54
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55
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56
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57
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- Updating Status Report for Water, Sediment and Fish
- Viacom to submit shortly the Long-Term Groundwater Monitoring Plan
- Appears Issue with fence surrounding landfill resolved
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58
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59
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- Total gallons treated as of 12/31/01 – 176,781,606
- Roll off-box sent for disposal on 2/4/02
- Roll-off sent to Safety-Kleen PPM in Ohio, then transferred to approved
landfill in Clive, Utah
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60
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- Two Storm Events: 12/14/01 and 12/17/01
- Peak flow on 12/17/01 – 2,777 gpm
- PCB peak – 28 ppb
- Volume Stored – 8,181,195 gallons
- Volume Overflowed (from tanks) – 6,353,035 gallons
- Total storm volume treated – 11,615,539 gallons
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61
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- Draft report received by EPA on February 2, 2002
- Tests conducted October 31 to November 23, 2001
- Data are preliminary and analysis is ongoing
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62
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- To determine if any of the wells surrounding the site were on or near a
major conduit which would integrate all three dyes into one flow path
towards the ICE
- To determine travel times from various areas of the site to the ICE
- To determine if Quarry B would receive dye under controlled flow
conditions, and hence could be presumed to be an Illinois Central
underflow discharge point
- To determine if pumping wells at Lemon Lane Landfill would impact PCB levels at ICE
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63
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- Multiple dye injections under natural gradient conditions (October 31 –
November 7)
- MW –21 Pump Test (November 7 – November 9)
- MW – 16 Pump Test (November 13 -
November 19)
- Injection test at Sargent’s Pond (November 20 - November 23)
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64
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- Eosine at NN700 10/31/01 at 10:15 (phreatic well open in the 795’ – 800’
zone)
- Phloxine B at SP1 10/31/01 at 11:15 (phreatic well open in the 795’ –
800’ zone)
- Fluorescein at LF6-8 10/31/01 at 11:50 (vadose “epikarst” well, high PCB
area)
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65
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66
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67
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- Fluorescein analytical results are regarded as semi quantitative
- Unambiguous detections of Fluorescein in several Valhalla wells (OO370, NN300,
NN300A, OO300 and OO300A)
- Epikarst flow from LF-6 area is predominately southwest, but descends to
the 795’ – 800’ phreatic zone near NN-370
- Very high dye concentrations suggest that these wells are located near a
primary conduit
- Single Fluorescein detection at 4S may be of questionable validity
- Travel time to ICE - 21 hours at 170 gpm average flow rate
- Fluorescein response at ICE indicates there may be more than pathway
from LF6 to the spring.
- Fluorescein in only one sample from Quarry B at background levels
- No breakthrough curve for Fluorescein at Swallowhole Seep
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68
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69
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70
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71
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- Difficult to detect Eosine in presence of large concentrations of
Fluorescein
- Eosine concentrations much lower than Fluorescein
- Eosine detected in Valhalla wells (OO-370, OO-587, OO-387, NN-300 and
NN-625)
- Eosine detected in Lemon Lane MW-15, -16, -18, -19, -20 and 21
- Ground water from NN-700 area flows east and northeast to MW-21 -
MAYBE!
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72
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73
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- Phloxine was not detected unambiguously in any well or spring.
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74
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- Could significant levels of PCBs be recovered from a pumping well?
- Would PCBs levels at ICE be reduced as a result of pumping?
- Pump on 11/7/01 10:00 Rate =
17 gpm
- Pump off on 11/9/01 14:00 52
hours
- Secondary dye flush at LF 6-8
11/8/01 15:30
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75
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- ICE flow rate reduced
- The well received some Fluorescein from LF- 6, but ICE received much
more
- PCBs at pumping well in the 5-7 ug/l range.
- Pumping did not lower the PCBs at ICE Spring after 52 hours, in fact PCB
levels appear to have increased at the onset of pumping
- MW-21 is not on or hydraulically well connected to a major conduit that
carries a large amount of PCBs to the ICE
- Pumping of MW-21 will not capture most of the materials that are flushed
from the epikarst near LF-6
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76
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77
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- Pump on 11/13/01 12:00 Rate =
17 gpm
- Pump off on 11/19/01 08:30 140
hours
- Secondary dye flush at LF 6-8
11/16/01 15:30
- Secondary dye flush at SP-1
11/14/01 15:30
- Secondary dye flush at NN700
11/15/01 11:30
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78
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- ICE flow rate reduced
- The well received some Fluorescein from second flush at LF- 6, but ICE
received much more
- PCBs at the pumping well decreased from 8 to 2.5-3 ug/l
- PCBs at ICE varied during pumping, and drops in PCBs were not consistent
or large enough to be considered a direct benefit of pumping
- MW-16 pumping will not significantly lower PCBs at ICE.
- Pumping of MW-16 will not capture most of the materials that are flushed
from the epikarst near LF6
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79
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80
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- 200,000 gallons treated water discharged to Sargent’s Pond
- No large rise in water levels observed in any monitoring well
- ICE may have shown a 4 –5 gpm flow increase
- Sargent’s Pond has a low seepage rate
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81
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